Photoinduced Electron Transfer to C60 across Extended 3- and 11-Bond Hydrocarbon Bridges: Creation of a Long-Lived Charge-Separated State
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منابع مشابه
Strong supramolecular binding of Li(+)@C60 with sulfonated meso-tetraphenylporphyrins and long-lived photoinduced charge separation.
A supramolecular binding occurred between lithium ion encapsulated [60]fullerene (Li(+)@C(60)) and sulfonated tetraphenylporphyrins ([MTPPS](4-) M = H(2) and Zn) in a benzonitrile solution. Photoexcitation of Li(+)@C(60)/[MTPPS](4-) results in formation of a long-lived charge-separated state by photoinduced electron transfer.
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